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Continuous Spectrum of Morphologies and Phase Behavior across the Contact Zone from Poly(l-lactid...The enantiomeric ratio is a key factor affecting the crystallization behavior and morphology of poly-l-lactide/poly-d-lactide (PLLA/PDLA) blends. Despite a number of studies on crystallization of nonequimolar PLLA/PDLA blends, a full picture of the effect of the L/D ratio is still lacking. Here, we put the two enant...
https://pubs.acs.org/doi/10.1021/acs.macromol.3c01815
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Poisoning by Purity: What Stops Stereocomplex Crystallization in Polylactide Racemate?Formation of stereocomplex crystals (SC) is an effective way to improve the heat resistance and mechanical performance of poly(lactic acid) products. However, at all but the slowest cooling rates, SC crystallization of a high-molecular-weight poly(L-lactic acid)/poly(D-lactic acid) (PLLA/PDLA) racemate stops at a hi...
https://pubs.acs.org/doi/epdf/10.1021/acs.macromol.2c02067
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